Linear variational Diophantine techniques in mass balance of chemical reactions
نویسنده
چکیده
Linear algebraic techniques based on minimization of thermodynamic functional and/or other constraints are illustrated for mass balance of chemical reactions that do not exhibit stoichiometrically unique solutions in the linear algebraic vector space. The techniques demonstrate elegant casting of chemical equations in terms of generalized linear Diophantine matrices and generalized elimination and variational schemes.
منابع مشابه
Variational Principle, Uniqueness and Reciprocity Theorems in Porous Piezothermoelastic with Mass Diffusion
The basic governing equations in anisotropic elastic material under the effect of porous piezothermoelastic are presented. Biot [1], Lord & Shulman [4] and Sherief et al. [5] theories are used to develop the basic equations for porous piezothermoelastic with mass diffusion material. The variational principle, uniqueness theorem and theorem of reciprocity in this model are established under the ...
متن کاملModeling of Reversible Chain Transfer Catalyzed Polymerization by Moment Equations Method
A moment equations method was performed to study the Reversible chain Transfer Catalyzed Polymerization (RTCP) of styrene in 80°C. To do this, a kinetic scheme containing conventional free radical polymerization reactions and equilibrium reactions of RTCP was assumed. After obtaining mass balance equations, three moment equations were defined for free and dormant radicals and dead chains. M...
متن کاملDiophantine Equations Related with Linear Binary Recurrences
In this paper we find all solutions of four kinds of the Diophantine equations begin{equation*} ~x^{2}pm V_{t}xy-y^{2}pm x=0text{ and}~x^{2}pm V_{t}xy-y^{2}pm y=0, end{equation*}% for an odd number $t$, and, begin{equation*} ~x^{2}pm V_{t}xy+y^{2}-x=0text{ and}text{ }x^{2}pm V_{t}xy+y^{2}-y=0, end{equation*}% for an even number $t$, where $V_{n}$ is a generalized Lucas number. This pape...
متن کاملSignificance of Chemical Decomposition of Chloroethyl Phenyl Sulfide (CEPS) using Zinc-Cadmium Oxide (ZnO-CdO) Nanocomposite
The zinc-cadmium oxide (ZnO-CdO) nanocomposites with different weight percentages of cadmium oxide (CdO) nanoparticles were successfully synthesized by the sonochemical method using zinc and cadmium nitrates as precursors to probe their nano-structured surfaces for the decomposition reactions of chloroethyl phenyl sulfide (CEPS) as a surrogate of sulfur mustard agent simulant. Scanning electron...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2002